Technical Guide

Nickel 201: Low-Carbon Pure Nickel & Chemical Processing

UNS N02201 / W.Nr. 2.4068 — Low-carbon commercially pure nickel with superior caustic resistance and high-temperature stability, eliminating graphitization risk above 315°C.

Nickel 201 low carbon pure nickel - Shanghai Hangbo Alloy
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Overview

Nickel 201 (UNS N02201 / W.Nr. 2.4068) is the low-carbon version of Nickel 200, with carbon content strictly controlled to 0.02% maximum. This reduction in carbon eliminates the risk of graphitization — the precipitation of carbon as graphite particles at temperatures above 315°C (600°F) — which can cause embrittlement and loss of integrity in standard-purity nickel. As a result, Nickel 201 is the preferred choice for high-temperature caustic soda (NaOH) production, food processing equipment, and any application where the material will be exposed to elevated temperatures in corrosive media.

The alloy consists of at least 99.0% nickel, with careful control of impurities such as iron, manganese, silicon, copper, and carbon. This high purity gives Nickel 201 exceptional resistance to a wide range of corrosive environments, particularly concentrated caustic alkalis at all concentrations and temperatures. It also offers excellent mechanical properties at both cryogenic and elevated temperatures, good thermal and electrical conductivity, and outstanding magnetostrictive properties that make it valuable in electronic and instrumentation applications.

Nickel 201 is produced by induction melting followed by refining to achieve the high purity required. It is typically supplied in the annealed condition, which optimizes ductility and formability. The alloy can be readily formed by cold working operations including bending, drawing, and pressing. Welding is performed using gas tungsten arc welding (GTAW) with matching filler metal ERNi-1, and the low carbon content minimizes the risk of carbide precipitation in the heat-affected zone.

At Hangbo Alloy Group, Nickel 201 is supplied in plate, sheet, strip, round bar, forging stock, and seamless tubing forms, all with full mill test reports and third-party inspection available. We serve customers in chemical processing, food manufacturing, electronics, and energy industries with reliable quality and competitive lead times.

Quick Specifications

N02201
2.4068
8.89 g/cm³
1435 – 1446 °C
345 – 655 MPa
110 – 345 MPa
1230 °C (intermittent)
40 – 55%

Chemical Composition (ASTM B160 / ASME SB-160)

Nickel 201 is specified with very high minimum nickel content and tightly controlled carbon to prevent graphitization. The chemistry is essentially the same as Nickel 200 except for the carbon limit, which is reduced from 0.15% maximum to 0.02% maximum.

ElementMin %Max %
Nickel (Ni)99.0
Carbon (C)0.02
Manganese (Mn)0.35
Iron (Fe)0.40
Sulfur (S)0.01
Silicon (Si)0.35
Copper (Cu)0.25

Physical Properties

Nickel 201 retains the outstanding physical properties of pure nickel: high thermal conductivity, excellent electrical conductivity, and good ductility from cryogenic temperatures up to moderately elevated temperatures. Its coefficient of thermal expansion is significantly lower than that of ferritic or austenitic stainless steels, making it advantageous in applications with thermal cycling.

PropertyValueUnit
Density8.89g/cm³
Melting Range1435 – 1446°C
Specific Heat (21°C)456J/kg·K
Thermal Conductivity (21°C)70W/m·K
Electrical Resistivity (21°C)0.085μΩ·m
Modulus of Elasticity (21°C)207GPa
Mean CTE (21–93°C)13.3μm/m·°C
Curie Temperature360°C

Mechanical Properties at Room Temperature

Nickel 201 is typically supplied in the annealed condition per ASTM B160. The annealed temper provides the best combination of ductility, formability, and corrosion resistance. Cold working significantly increases strength and hardness but reduces ductility, which can be restored by annealing at 700–900°C depending on Section thickness and desired grain size.

ConditionTensile Strength (MPa)Yield Strength (MPa)Elongation (%)
Annealed (Plate/Sheet)380 – 520110 – 34040 – 55
Annealed (Bar)345 – 655110 – 34540 – 50
1/4 Hard400 – 550275 – 41525 – 40
1/2 Hard480 – 620415 – 55015 – 30
Full Hard620 – 860550 – 7905 – 15

High-Temperature Performance & Graphitization Resistance

The defining advantage of Nickel 201 over Nickel 200 is its resistance to graphitization at elevated temperatures. In standard-purity nickel (0.10–0.15% C), carbon can precipitate as graphite particles when the material is held above approximately 315°C (600°F) for extended periods. These graphite particles create weak interfaces that can lead to intergranular cracking under stress.

By limiting carbon to 0.02% maximum, Nickel 201 suppresses graphite formation and maintains its ductility and strength even after long-term exposure to temperatures up to approximately 1230°C (2250°F) in intermittent service, or up to 600°C (1110°F) in continuous service. This makes Nickel 201 the correct choice for:

  • Caustic Soda (NaOH) Production: Evaporator tubes and headers operating at 450–500°C where Nickel 200 would eventually graphitize.
  • Food Processing: High-temperature cooking and sterilization equipment where purity and corrosion resistance are both critical.
  • Heat Exchangers: Where thermal cycling could otherwise cause graphite-related embrittlement.

At elevated temperatures, Nickel 201 retains useful strength up to approximately 600°C in continuous service. Above this temperature, oxidation becomes the limiting factor, although the alloy forms a protective nickel oxide scale that provides reasonable protection in air up to approximately 980°C for intermittent exposure.

Corrosion Resistance

Nickel 201 offers the same excellent corrosion resistance as Nickel 200, with the added advantage of high-temperature stability. Its corrosion performance is governed by the formation of a stable, adherent surface oxide film that protects the underlying metal in many oxidizing and reducing environments.

Key Corrosion Resistances:

  • Caustic Alkalis (NaOH, KOH): Outstanding resistance to concentrated caustic solutions at all temperatures up to the boiling point. This is the primary application driver for both Nickel 200 and 201.
  • Neutral and Alkaline Salt Solutions: Resistant to most neutral and alkaline salt solutions, including carbonates, nitrates, and bicarbonates.
  • Fresh Water and Steam: Excellent resistance to corrosion by fresh water, including high-purity water used in power generation and pharmaceutical applications.
  • Food Acids: Good resistance to many food acids (citric, lactic, tartaric) at moderate temperatures and concentrations.
  • Dry Gases: Resistant to dry chlorine, hydrogen chloride, and fluoride gases up to approximately 540°C.
  • Oxidizing Conditions: More resistant to oxidizing media than the high-nickel-molybdenum alloys (Hastelloy series), but less resistant than chromium-bearing stainless steels in strongly oxidizing acids such as nitric acid.

Applications

Nickel 201 is specified wherever high-purity nickel is required in a corrosive environment at elevated temperature, particularly where caustic alkalis are present.

  • Chemical Processing: Caustic soda evaporators, headers, and piping systems; soap and detergent manufacturing equipment; mercuric oxide cells in chlor-alkali production.
  • Food and Beverage: Processing vessels, heat exchanger components, and conveyor systems where product purity and corrosion resistance are essential.
  • Electronics and Instrumentation: Lead wires, terminals, and structural components in vacuum tubes, transistors, and temperature controllers, leveraging the alloy's magnetostrictive properties and low vapor pressure.
  • Aerospace and Defense: Aerospace fasteners and structural components requiring good strength at both cryogenic and moderately elevated temperatures, and where contamination from iron-bearing alloys must be avoided.
  • Hydrogen Storage and Handling: Nickel 201 is virtually immune to hydrogen embrittlement and is used in hydrogen gas handling systems, including storage vessels and transfer lines.
  • Petrochemical: Reactor internals and piping in processes using caustic washing or where resistance to sour gas (controlled H2S) is required at moderate temperatures.

Available Product Forms

Hangbo Alloy Group supplies Nickel 201 in a full range of product forms with material test reports and third-party inspection available on request.

  • Plates & Sheets: ASTM B160 / ASME SB-160, thickness 0.5 mm to 50 mm, annealed, for chemical equipment fabrication.
  • Round Bars: ASTM B160, diameters 6 mm to 300 mm, annealed, for machined components and fasteners.
  • Seamless Tubes: ASTM B161 / ASME SB-161, OD 6 mm to 219 mm, for heat exchangers and process piping.
  • Forgings: Open-die and ring-rolled forgings, custom shapes, heat treated and ultrasonic tested.
  • Welding Wire: AWS A5.14 ERNi-1, precision layer-wound, for welding Nickel 200/201 components and clad steel transitions.

Related Standards

StandardDescription
ASTM B160Rod and Bar
ASTM B161Seamless Pipe and Tube
ASTM B162Plate, Sheet, and Strip
ASTM B163Seamless Condenser and Heat Exchanger Tubes
ASME SB-160 / SB-163Boiler and Pressure Vessel Code
AWS A5.14Welding Wire (ERNi-1)
DIN 17740Ni 99.2 (W.Nr. 2.4068)

Nickel 200 vs. Nickel 201 — Which to Choose?

The primary selection criterion between Nickel 200 and Nickel 201 is service temperature. For service below approximately 315°C (600°F), Nickel 200 is typically adequate and more economical. For service above 315°C, or where the material will be heated into that range during fabrication or operation, Nickel 201 is mandatory to avoid graphitization. For cryogenic service (down to −250°C), either grade may be used, with Nickel 201 offering slightly better toughness retention after high-temperature exposure.

Contact Us for Nickel 201

Hangbo Alloy Group maintains mill-direct supply of Nickel 201 plates, sheets, bars, tubes, and welding wire. Our technical team can assist with material selection, formability guidance, welding procedure review, and export documentation. We support chemical processing, food manufacturing, electronics, and energy industry customers with short lead times and reliable quality.

For quotations, material certifications, or technical consultation, contact our sales team or call +86-136-1165-6360. We typically respond within 10 minutes.

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